Double-Edge is learned by 190 species by level, 459 by machine, 364 by tutor and 50 by egg

Effect, in PokéAPI's words

“User receives 1/3 the damage inflicted in recoil.”

Who learns it

600 species in all, 3 of 25 games shown

Scarlet and Violet: 383 species

Species	Method	Level
Wigglytuff	Level up, Machine	1
Vaporeon	Level up, Machine	1
Jolteon	Level up, Machine	1
Flareon	Level up, Machine	1
Typhlosion	Level up, Machine	1
Espeon	Level up, Machine	1
Umbreon	Level up, Machine	1
Leafeon	Level up, Machine	1
Glaceon	Level up, Machine	1
Volcarona	Level up, Machine	1
Sylveon	Level up, Machine	1
Marill	Level up, Machine	33
Fidough	Level up, Machine	33
Sunkern	Level up, Machine	34
Sunflora	Level up, Machine	34
Lechonk	Level up, Machine	35
Scorbunny	Level up, Machine	36
Deerling	Level up, Machine	37
Skiddo	Level up, Machine	38
Dachsbun	Level up, Machine	38
Geodude	Level up, Machine	40
Chansey	Level up, Machine	40
Blissey	Level up, Machine	40
Gogoat	Level up, Machine	40
Sentret	Level up, Machine	42
Phanpy	Level up, Machine	42
Chimecho	Level up, Machine	42
Bergmite	Level up, Machine	42
Oinkologne	Level up, Machine	42
Volbeat	Level up, Machine	43
Minior	Level up, Machine	43
Jigglypuff	Level up, Machine	44
Sudowoodo	Level up, Machine	44
Bonsly	Level up, Machine	44
Hippopotas	Level up, Machine	44
Sawsbuck	Level up, Machine	44
Azumarill	Level up, Machine	45
Pineco	Level up, Machine	45
Passimian	Level up, Machine	45
Avalugg	Level up, Machine	46
Numel	Level up, Machine	47
Dunsparce	Level up, Machine	48
Raboot	Level up, Machine	48
Arrokuda	Level up, Machine	48
Dudunsparce	Level up, Machine	48
Maschiff	Level up, Machine	49
Cetoddle	Level up, Machine	49
Cetitan	Level up, Machine	49
Graveler	Level up, Machine	50
Golem	Level up, Machine	50
Eevee	Level up, Machine	50
Porygon	Level up, Machine	50
Furret	Level up, Machine	50
Forretress	Level up, Machine	50
Hippowdon	Level up, Machine	50
Porygon-Z	Level up, Machine	50
Cyclizar	Level up, Machine	51
Basculin	Level up, Machine	52
Basculegion	Level up, Machine	52
Greavard	Level up, Machine	52
Poliwag	Level up, Machine	54
Cinderace	Level up, Machine	54
Tauros	Level up, Machine	55
Cyndaquil	Level up, Machine	55
Stantler	Level up, Machine	55
Bagon	Level up, Machine	55
Wyrdeer	Level up, Machine	55
Mabosstiff	Level up, Machine	55
Barraskewda	Level up, Machine	56
Houndstone	Level up, Machine	58
Larvesta	Level up, Machine	60
Dondozo	Level up, Machine	60
Quilava	Level up, Machine	64
Poliwhirl	Level up, Machine	66
Drakloak	Level up, Machine	66
Glastrier	Level up, Machine	66
Spectrier	Level up, Machine	66
Shelgon	Level up, Machine	67
Dragapult	Level up, Machine	70
Terapagos	Level up, Machine	70
Salamence	Level up, Machine	73
Jirachi	Level up, Machine	77
Kyogre	Level up, Machine	81
Roaring Moon	Level up, Machine	91
Bulbasaur	Machine
Ivysaur	Machine
Venusaur	Machine
Charizard	Machine
Squirtle	Machine
Wartortle	Machine
Blastoise	Machine
Ekans	Machine
Arbok	Machine
Sandshrew	Machine
Sandslash	Machine
Clefairy	Machine
Clefable	Machine
Vulpix	Machine
Ninetales	Machine
Venomoth	Machine
Diglett	Machine
Dugtrio	Machine
Meowth	Machine
Persian	Machine
Psyduck	Machine
Golduck	Machine
Mankey	Machine
Primeape	Machine
Growlithe	Machine, Egg
Arcanine	Machine
Poliwrath	Machine, Egg
Doduo	Machine
Dodrio	Machine
Seel	Machine
Dewgong	Machine
Drowzee	Machine
Hypno	Machine
Voltorb	Machine
Electrode	Machine
Exeggutor	Machine
Hitmonlee	Machine
Hitmonchan	Machine
Rhyhorn	Machine
Rhydon	Machine
Electabuzz	Machine
Magmar	Machine
Gyarados	Machine
Lapras	Machine
Snorlax	Machine, Egg
Articuno	Machine
Moltres	Machine
Mewtwo	Machine
Mew	Machine
Chikorita	Machine
Bayleef	Machine
Meganium	Machine
Totodile	Machine
Croconaw	Machine
Feraligatr	Machine
Noctowl	Machine
Chinchou	Machine
Lanturn	Machine
Igglybuff	Machine
Mareep	Machine
Flaaffy	Machine
Ampharos	Machine
Politoed	Machine, Egg
Hoppip	Machine
Skiploom	Machine
Jumpluff	Machine
Aipom	Machine
Yanma	Machine, Egg
Wooper	Machine
Quagsire	Machine
Murkrow	Machine
Girafarig	Machine
Gligar	Machine, Egg
Snubbull	Machine
Granbull	Machine
Qwilfish	Machine
Scizor	Machine
Heracross	Machine, Egg
Teddiursa	Machine, Egg
Ursaring	Machine
Swinub	Machine, Egg
Piloswine	Machine, Egg
Houndour	Machine
Houndoom	Machine
Kingdra	Machine
Donphan	Machine
Porygon2	Machine
Hitmontop	Machine
Elekid	Machine
Magby	Machine
Raikou	Machine
Entei	Machine
Suicune	Machine
Larvitar	Machine
Pupitar	Machine
Tyranitar	Machine
Lugia	Machine
Ho-Oh	Machine
Sceptile	Machine
Torchic	Machine
Combusken	Machine
Blaziken	Machine
Mudkip	Machine, Egg
Marshtomp	Machine, Egg
Swampert	Machine, Egg
Poochyena	Machine
Mightyena	Machine
Lotad	Machine
Lombre	Machine
Ludicolo	Machine
Seedot	Machine
Nuzleaf	Machine
Shiftry	Machine
Vigoroth	Machine
Slaking	Machine
Makuhita	Machine
Hariyama	Machine
Nosepass	Machine, Egg
Illumise	Machine
Swalot	Machine
Camerupt	Machine
Torkoal	Machine
Flygon	Machine
Altaria	Machine
Zangoose	Machine
Seviper	Machine
Barboach	Machine
Whiscash	Machine
Corphish	Machine, Egg
Crawdaunt	Machine, Egg
Feebas	Machine
Milotic	Machine
Tropius	Machine
Metang	Machine
Metagross	Machine
Regirock	Machine
Registeel	Machine
Latias	Machine
Latios	Machine
Groudon	Machine
Rayquaza	Machine
Turtwig	Machine, Egg
Grotle	Machine, Egg
Torterra	Machine, Egg
Chimchar	Machine
Monferno	Machine
Infernape	Machine
Prinplup	Machine
Empoleon	Machine
Starly	Machine, Egg
Staravia	Machine
Staraptor	Machine
Shinx	Machine
Luxio	Machine
Luxray	Machine
Cranidos	Machine
Rampardos	Machine
Shieldon	Machine
Bastiodon	Machine
Floatzel	Machine
Ambipom	Machine
Honchkrow	Machine
Chingling	Machine
Stunky	Machine, Egg
Skuntank	Machine
Gible	Machine, Egg
Gabite	Machine
Garchomp	Machine
Munchlax	Machine, Egg
Snover	Machine, Egg
Abomasnow	Machine
Magnezone	Machine
Rhyperior	Machine
Electivire	Machine
Magmortar	Machine
Yanmega	Machine, Egg
Gliscor	Machine, Egg
Mamoswine	Machine, Egg
Probopass	Machine, Egg
Mesprit	Machine
Azelf	Machine
Regigigas	Machine
Shaymin	Machine
Arceus	Machine
Snivy	Machine
Servine	Machine
Serperior	Machine
Tepig	Machine
Pignite	Machine
Emboar	Machine
Blitzle	Machine
Zebstrika	Machine
Drilbur	Machine
Excadrill	Machine
Timburr	Machine
Gurdurr	Machine
Conkeldurr	Machine
Sandile	Machine, Egg
Krokorok	Machine
Krookodile	Machine
Scraggy	Machine
Scrafty	Machine
Cinccino	Machine
Ducklett	Machine
Swanna	Machine
Axew	Machine
Fraxure	Machine
Haxorus	Machine
Beartic	Machine
Mienshao	Machine
Golett	Machine
Golurk	Machine
Rufflet	Machine
Braviary	Machine
Vullaby	Machine
Mandibuzz	Machine
Cobalion	Machine
Terrakion	Machine
Virizion	Machine
Reshiram	Machine
Zekrom	Machine
Keldeo	Machine
Chesnaught	Machine
Fletchling	Machine
Fletchinder	Machine
Talonflame	Machine
Litleo	Machine
Pyroar	Machine
Carbink	Machine
Noivern	Machine
Volcanion	Machine
Litten	Machine
Torracat	Machine
Incineroar	Machine
Yungoos	Machine
Gumshoos	Machine
Rockruff	Machine
Lycanroc	Machine
Mudbray	Machine, Egg
Mudsdale	Machine
Komala	Machine
Hakamo-o	Machine
Kommo-o	Machine
Solgaleo	Machine
Thwackey	Machine
Rillaboom	Machine
Skwovet	Machine
Greedent	Machine
Corviknight	Machine
Drednaw	Machine
Perrserker	Machine
Eiscue	Machine, Egg
Morpeko	Machine
Cufant	Machine, Egg
Copperajah	Machine
Duraludon	Machine
Kubfu	Machine
Urshifu	Machine
Zarude	Machine
Kleavor	Machine
Ursaluna	Machine
Overqwil	Machine
Lokix	Machine
Pawmot	Machine
Tandemaus	Machine
Maushold	Machine
Squawkabilly	Machine, Egg
Naclstack	Machine
Garganacl	Machine
Shroodle	Machine
Grafaiai	Machine
Espathra	Machine
Varoom	Machine
Revavroom	Machine
Orthworm	Machine
Veluza	Machine
Annihilape	Machine
Clodsire	Machine
Farigiraf	Machine
Great Tusk	Machine
Scream Tail	Machine
Brute Bonnet	Machine
Slither Wing	Machine
Iron Treads	Machine
Iron Hands	Machine
Iron Jugulis	Machine
Iron Thorns	Machine
Baxcalibur	Machine
Ting-Lu	Machine
Koraidon	Machine
Walking Wake	Machine
Iron Leaves	Machine
Okidogi	Machine
Archaludon	Machine
Hydrapple	Machine
Gouging Fire	Machine
Raging Bolt	Machine
Iron Boulder	Machine
Iron Crown	Machine

Legends Arceus: 82 species

Species	Method	Level
Lickitung	Level up	25
Lickilicky	Level up	25
Starly	Level up	29
Staravia	Level up	29
Staraptor	Level up	29
Machop	Level up	34
Machoke	Level up	34
Machamp	Level up	34
Rufflet	Level up	34
Geodude	Level up	37
Graveler	Level up	37
Golem	Level up	37
Ponyta	Level up	37
Rapidash	Level up	37
Sudowoodo	Level up	37
Heracross	Level up	37
Cranidos	Level up	37
Rampardos	Level up	37
Cherubi	Level up	37
Cherrim	Level up	37
Bonsly	Level up	37
Gible	Level up	37
Gabite	Level up	37
Garchomp	Level up	37
Bidoof	Level up	40
Bibarel	Level up	40
Buneary	Level up	40
Lopunny	Level up	40
Glameow	Level up	40
Purugly	Level up	40
Rhyhorn	Level up	43
Rhydon	Level up	43
Chansey	Level up	43
Eevee	Level up	43
Vaporeon	Level up	43
Jolteon	Level up	43
Flareon	Level up	43
Aipom	Level up	43
Espeon	Level up	43
Umbreon	Level up	43
Teddiursa	Level up	43
Ursaring	Level up	43
Blissey	Level up	43
Chimecho	Level up	43
Turtwig	Level up	43
Grotle	Level up	43
Torterra	Level up	43
Chimchar	Level up	43
Monferno	Level up	43
Infernape	Level up	43
Piplup	Level up	43
Prinplup	Level up	43
Empoleon	Level up	43
Ambipom	Level up	43
Chingling	Level up	43
Stunky	Level up	43
Skuntank	Level up	43
Happiny	Level up	43
Hippopotas	Level up	43
Hippowdon	Level up	43
Rhyperior	Level up	43
Leafeon	Level up	43
Glaceon	Level up	43
Sylveon	Level up	43
Ursaluna	Level up	43
Basculegion	Level up	43
Snorlax	Level up	46
Munchlax	Level up	46
Clefairy	Level up	47
Clefable	Level up	47
Cleffa	Level up	47
Mantine	Level up	47
Stantler	Level up	47
Shieldon	Level up	47
Bastiodon	Level up	47
Mantyke	Level up	47
Bergmite	Level up	47
Wyrdeer	Level up	47
Overqwil	Level up	47
Swinub	Level up	52
Piloswine	Level up	52
Mamoswine	Level up	52

Brilliant Diamond and Shining Pearl: 100 species

Species	Method	Level
Wigglytuff	Level up	1
Poliwrath	Level up	1
Vaporeon	Level up	1
Jolteon	Level up	1
Flareon	Level up	1
Typhlosion	Level up	1, 69
Politoed	Level up	1
Espeon	Level up	1
Umbreon	Level up	1
Donphan	Level up	1
Delcatty	Level up	1
Camerupt	Level up	1
Togekiss	Level up	1
Leafeon	Level up	1
Glaceon	Level up	1
Rattata	Level up	31
Togepi	Level up	32
Togetic	Level up	32
Bulbasaur	Level up	33
Marill	Level up	33
Zigzagoon	Level up	36
Sunkern	Level up	37
Sunflora	Level up	37
Raticate	Level up	39
Geodude	Level up	40
Chansey	Level up	40
Ledyba	Level up	40
Blissey	Level up	40
Skitty	Level up	40
Phanpy	Level up	42
Chimecho	Level up	42
Jigglypuff	Level up	44
Sudowoodo	Level up	44
Bonsly	Level up	44
Hippopotas	Level up	44
Ivysaur	Level up	45
Azumarill	Level up	45
Pineco	Level up, Egg	45
Spinda	Level up	46
Ledian	Level up	47
Volbeat	Level up	47
Numel	Level up	47
Cubone	Level up	48
Linoone	Level up	48
Graveler	Level up	50
Golem	Level up	50
Eevee	Level up	50
Forretress	Level up	50
Relicanth	Level up	50
Hippowdon	Level up	50
Venusaur	Level up	51
Machop	Level up	52
Dunsparce	Level up	52
Poliwag	Level up	54
Tauros	Level up	55
Cyndaquil	Level up, Egg	55
Stantler	Level up	55
Bagon	Level up	55
Onix	Level up	56
Steelix	Level up	56
Aron	Level up	56
Marowak	Level up	60
Quilava	Level up	64
Poliwhirl	Level up	66
Machoke	Level up	66
Machamp	Level up	66
Shelgon	Level up	67
Lairon	Level up	70
Salamence	Level up	73
Jirachi	Level up	77
Aggron	Level up	80
Kyogre	Level up	81
Growlithe	Egg
Ponyta	Egg
Kangaskhan	Egg
Snorlax	Egg
Sentret	Egg
Hoppip	Egg
Yanma	Egg
Gligar	Egg
Snubbull	Egg
Heracross	Egg
Teddiursa	Egg
Swinub	Egg
Miltank	Egg
Mudkip	Egg
Nosepass	Egg
Carvanha	Egg
Wailmer	Egg
Corphish	Egg
Absol	Egg
Turtwig	Egg
Starly	Egg
Bidoof	Egg
Cranidos	Egg
Shieldon	Egg
Stunky	Egg
Gible	Egg
Munchlax	Egg
Snover	Egg

Changed over time

One change since Generation I

1. Through Gen IPower 100120 from Gold and Silver, Generation II