Moves, #164, Substitute
Substitute is learned by 14 species by level, 999 by machine, 372 by tutor and 17 by egg
Of the 1,025 species this site covers, default forms only
Effect, in PokéAPI's words
“Transfers 1/4 of the user’s max HP into a doll, protecting the user from further damage or status changes until it breaks.”
Who learns it